FWIW, I have a netbook (Windows 7) which does something interesting.  I bring it up because it is something that may be applicable to CentOS.
There is a tunneling pseudo-interface which is only IPv6; it has two addresses, the IPv6 address, and a local-link IPv6 address.  The hardware interfaces also have two addresses, an IPv6 local-link back to the tunnel, and an IPv4 address given by the router.
However, I am not sure that this is efficient for anything other than a light-use personal machine, and unfortunately I'm not sure what happens when it is connected to an IPv6 router! ):
Attached is a screen shot since I'm not sure that my description gave it justice.

Rob

On Sun, Dec 5, 2010 at 8:21 AM, Tom H <tomh0665@gmail.com> wrote:
On Sun, Dec 5, 2010 at 8:13 AM, RedShift <redshift@pandora.be> wrote:
> On 12/05/10 12:50, Rudi Ahlers wrote:
>>
>> (http://www.internetnews.com/infra/article.php/3915471/IPv4+Nearing+Final+Days.htm),
>
> Haven't switched yet, I have IPv6 at home using sixxs.
>
> I can't even figure out what address ranges are reserved for private use, is there even such a concept in IPv6?

I think that site-local ("fec0:: - fef::") is the ipv6
more-or-less-equivalent of ipv4 private addresses.
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